PEER-REVIEWED PUBLICATION

2025

Electrically Conductive 3D-Printed Piezoresistive Metastructure Lattice Sensors

Mukherjee A, Pulikkunnel PJ, et al.

ACS Applied Electronic Materials

University of Groningen, Engineering and Technology Institute Groningen (ENTEG), Zernike Institute for Advanced Materials (ZIAM)

RESEARCH SUMMARY
This study reports electrically conductive, high-resolution SLA 3D-printed metastructure lattice sensors engineered for wearable force sensing (human gait monitoring) with programmable mechanical response. Flexible lattice microarchitectures (tetra, X, hexa, W, soft box, vin tiles) were printed in an elastic resin and then functionalized using two contrasting conductive coating routes: (i) wet dip-coating with titanium carbide (TiC) ink to create percolating conductive pathways and microcrack-mediated piezoresistivity, and (ii) dry oxidative chemical vapor deposition (oCVD) to conformally deposit doped polypyrrole (PPy) networks yielding continuous positive piezoresistive response. Mechanical stiffness and load-bearing capacity were tuned by topology, with the tetra lattice selected as an optimized structure balancing stiffness, plateau deformation behavior, low hysteresis, and cyclic repeatability. Electromechanical sensing performance was characterized under both static and dynamic compressive loading, demonstrating broad detection ranges (reported up to 180 N), gauge factors in the ~12–13 range (depending on coating/system), and stable cyclic output (<5% variation) across low-force (down to 0.2 N) and high-force (up to 90 N) cycling. Practical applicability was demonstrated by integrating TiC-coated lattice sensors into a monolithically fabricated shoe insole and capturing distinct heel/toe loading signals during treadmill walking, supporting personalized wearable gait-monitoring and rehabilitation applications.

CELLSCALE INSTRUMENT USED

UniVert

Uniaxial compression and electromechanical force-sensing characterization were performed using a CellScale UniVert micromechanical tester equipped with a 200 N load cell. For mechanical characterization, pristine and coated lattice cubes (including topology-screening prints and optimized tetra lattices) were compressed under ambient conditions while recording force and displacement; the paper reports recording displacement over time in response to a controlled applied-force ramp (0.2 N/min) and computing lattice stiffness from the force–displacement response (n=3). For sensor characterization, the UniVert applied controlled static and dynamic compressive forces while electrical resistance changes were recorded: TiC-coated lattices were instrumented with conductive copper plates (25×25 mm) bonded to opposing faces using conductive silver epoxy (cured at 125°C for 60 min), wired into an external Wheatstone bridge/DAQ, and tested both as free-standing lattices and as lattices embedded within a solid elastic block; the setup isolated metallic tester connections with nonconductive tape to prevent electrical interference. oCVD PPy-coated lattices were similarly tested under UniVert-applied static and cyclic compressive forces using attached electrodes/copper tape. Dynamic loading experiments included low-force cycling down to 0.2 N and higher-force cyclic regimes (tens of newtons up to ~90 N) with frequency variation (reported 0.2–2 Hz in the study), enabling quantification of repeatability and drift under gait-relevant conditions.
AUTHORS

Adrivit Mukherjee, Pranav Joseph Pulikkunnel, Sara Selenica, Amar M. Kamat, Srikanth Birudula, Marleen Kamperman, Ranjita K. Bose, Ajay Giri Prakash Kottapalli.

PUBLICATION DETAILS
JOURNAL

ACS Applied Electronic Materials

YEAR

2025

INSTITUTIONS

University of Groningen, Engineering and Technology Institute Groningen (ENTEG), Zernike Institute for Advanced Materials (ZIAM)

COUNTRIES

Netherlands

INSTRUMENT USED

UniVert

TESTING METHODS

Compression TestingFatigue TestingUltra Low Force Testing

RESEARCH APPLICATIONS

Polymers and Elastomers TestingSoft Robotics MaterialsWearable Bioelectronics

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